The number 5 doesn't necessarily refer to the cylinder number, no. I found that when I pulled my 351 down, I had numbers ranging from 1 through to 6, totally at random and not consistent with any of the cylinder bores. It had never been opened up before, so I'm none the wiser. Maybe they are casting numbers, although they stamped, so... I dunno...
Just make sure you keep the pistons in order as bores and pistons will wear at different rates, says the engineGod that is Tom Monroe. I'm sure you know this, but just in case you didn't... I re-used my stock pistons in my build as well. Expensive aren't they..?