Same time ideally. If you bump up your injector size, you either compensate by "tricking" the computer with a new MAF, or you have to get some computer work (uni-chip, tweecer etc etc).
As Sparkles said, injectors are cheap in the US (better than the $350 EACH I was quoted the other day for 19lbs from Ford). Another good thing, MAFs are cheap too.
Also, its a very good idea to check your A/F ratio after changes such as this. Even though the MAF & Injectors are supposed to be right, they can still be out, and a lean condition is baaaad mmkay !
No prizes for guessing what I'm doing in the next couple of weeks