Brazing should never be done any car (unless its electric silicone bronze) as the flux's used for brazing are corrosive. It is howver ok,IF you can clean up both sides.
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It is almost never done correctly by a professional on the first attempt.
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I must be lucky then!!!
My first attempt came out perfect...not bad for a bloke from a smash background!
On the original question, Mustangs seem to fare better than most other marques, as the lower cowl was galvanised from factory. This at least gave the unpainted area's a chance. As your freind suggest a car sitting has a higher probability of issues, as this allows water to sit in lower lying area's. Movement of the vehicle permits, the water to move about and head for the drains.
Even with movement, life under trees can generate problems, as leaves block the drains quite readily, and this stands for ANY car. I have seen cowl leaks repaired simply by blowing out all the crap that has accumulated, and unfortunatley for an early stang this often means guard removal any how.
As our learned friend above suggests, a top cowl removal can be problematic if care is not taken with alignment on reassembly. There are two factors to ensure proper realignment.
1) before you begin, drill 2 1/8" holes through the windsreen lip, and 2 through the firewall lip...in an area that is not going to be replaced. (don't put em in spot welds) Upon reassembly, putting self tappers through these 4 holes will place the top cowl so close to factory that the tolerances originally built in will ensure proper panel alignment later.
2) The manner in which you unpick the spots. (on a 65/66 there are 142 welds) The ONLY way is with a flat bottomed spot weld drill. You can buy them commercially, but i prefer to grind my own. The best thing youcould do i s buy one commercially, and then use it as a reference to cut your own. that way you can make a few in different sizes to suit different size spots.
Cheers.
Jas